3.2 Resistivity, Its Temperature Dependence and Electrical Power
Not everything obeys Ohm's law, resistivity spans more than twenty powers of ten from silver to glass, metals resist more when hot while semiconductors resist less — and every resistor turns electrical energy into heat at the rate $P=VI=I^2R$.
Measure the resistance of a 60 W filament bulb with a multimeter and you get a few tens of ohms. Yet at its working voltage of $230$ V it draws only about a quarter of an ampere, which means a resistance near $900\ \Omega$. Nothing is wrong with the meter: the filament at $2500\ ^\circ\text{C}$ is a very different conductor from the same filament at room temperature. The same physics makes a toaster element glow, lets a platinum wire act as a precise thermometer in a laboratory or a hospital, and makes the thermistor in a phone charger cut the current when the battery warms up.
In Section 3.1 we met Ohm's law and the resistivity $\rho$ of a material, and explained both with the drift of free electrons. This section asks where Ohm's law fails, compares the resistivities of real materials, studies how resistivity changes with temperature (with the temperature coefficient of resistivity $\alpha$), and finally works out the electrical power delivered to a resistor — the energy behind every heater, every electricity bill and every power line.
Where Ohm's Law Fails
Ohm's law is not a law of nature in the way that conservation of charge is. It is an observed property of many materials — metals at a steady temperature above all — and it is so useful that we name devices after whether they obey it.
Devices depart from Ohm's law in three typical ways:
- $V$ is not proportional to $I$. A filament lamp: as the current grows, the filament heats up and its resistance rises, so the $I$–$V$ curve bends towards the $V$-axis. A thermistor does the opposite: as it warms up its resistance falls and the curve bends upwards.
- The relation depends on the sign of $V$. A semiconductor diode (Chapter 14) lets a large current through in one direction and almost none in the other.
- The relation is not unique. In some devices (gallium arsenide, for instance) the same current flows at more than one voltage: over part of the graph, the current falls as the voltage rises.
Even a perfectly ohmic metal wire becomes "non-ohmic" if it is allowed to heat up. Ohm's law is a statement about a material at a fixed temperature; the filament lamp is a metal whose temperature changes with the current.
Resistivity of Various Materials
Resistivity varies enormously from one material to another — far more than almost any other physical property. A centimetre cube of silver has a resistance of about $10^{-6}\ \Omega$; a centimetre cube of glass can have $10^{12}\ \Omega$ or more. Materials fall into three broad groups:
- Conductors (metals and alloys): $\rho\sim10^{-8}$ to $10^{-6}\ \Omega\ \text{m}$. Plenty of free electrons, $n\sim10^{28}$–$10^{29}\ \text{m}^{-3}$.
- Semiconductors (silicon, germanium): intermediate resistivities that fall as the temperature rises and can be changed enormously by adding tiny amounts of impurity (Chapter 14).
- Insulators (glass, rubber, plastics, ceramics): $\rho\sim10^{11}$ to $10^{19}\ \Omega\ \text{m}$. Almost no free charge carriers.
| Material | $\rho$ at $20\ ^\circ\text{C}$ ($\Omega\ \text{m}$) | $\alpha$ ($^\circ\text{C}^{-1}$) | Typical use |
|---|---|---|---|
| silver | $1.6\times10^{-8}$ | $3.8\times10^{-3}$ | contacts, conductive inks |
| copper | $1.7\times10^{-8}$ | $3.9\times10^{-3}$ | house wiring, motor windings |
| aluminium | $2.7\times10^{-8}$ | $4.0\times10^{-3}$ | overhead power lines |
| tungsten | $5.6\times10^{-8}$ | $4.5\times10^{-3}$ | lamp filaments |
| platinum | $1.1\times10^{-7}$ | $3.9\times10^{-3}$ | resistance thermometers |
| manganin (alloy) | $4.4\times10^{-7}$ | $\approx2\times10^{-6}$ | standard resistors |
| nichrome (alloy) | $1.1\times10^{-6}$ | $4\times10^{-4}$ | heating elements |
| silicon (pure) | $\approx2\times10^{3}$ | negative | chips (after doping) |
Approximate values; real samples vary with purity and treatment. Two alloys stand out. Nichrome (nickel–chromium) has a resistivity about $65$ times that of copper and does not oxidise when red hot — ideal for heater elements. Manganin and constantan have resistivities that hardly change with temperature, so resistors made from them keep their value when they warm up; they are used for standard resistors and precision instruments.
Temperature Dependence of Resistivity
Heat a copper wire from room temperature to $100\ ^\circ\text{C}$ and its resistance rises by about $30\%$. Over a moderate range of temperature the increase is very nearly linear, which suggests describing it by the fractional change of resistivity per degree.
Metals: $\alpha\gt0$, of the order of $4\times10^{-3}\ ^\circ\text{C}^{-1}$; the resistivity rises nearly linearly with temperature over a wide range (it curves at very low temperatures).
Alloys such as nichrome, manganin and constantan: $\alpha\gt0$ but very small, so their resistivity is almost independent of temperature.
Semiconductors: the resistivity decreases rapidly as the temperature rises ($\alpha\lt0$, and not constant), and insulators behave in the same way.
All three follow from $\rho=\dfrac{m}{ne^2\tau}$ (Result 3.2).
Why metals resist more when hot. In a metal the number $n$ of free electrons per unit volume hardly changes with temperature. But the ions of the lattice vibrate more vigorously as the metal warms up, so the electrons collide with them more often: the relaxation time $\tau$ falls, and $\rho\propto1/\tau$ rises. Why semiconductors resist less when hot. In a semiconductor $n$ is small at room temperature, because most electrons are bound. Heating frees more of them — $n$ grows very steeply with temperature, far outweighing the small fall in $\tau$ — so $\rho\propto1/n$ falls. A device built on this effect is a thermistor with a negative temperature coefficient (an NTC thermistor), the most common temperature sensor in electronics.
- Identify the reference temperature $T_0$ at which $R_0$ (or $\rho_0$) and $\alpha$ are quoted — often $0\ ^\circ\text{C}$ or $20\ ^\circ\text{C}$.
- For a single unknown use $R_T=R_0[1+\alpha(T-T_0)]$ directly, or its rearrangement $T-T_0=\dfrac{R_T-R_0}{\alpha R_0}$.
- If two readings $R_1$ at $T_1$ and $R_2$ at $T_2$ are given and $\alpha$ is referred to $0\ ^\circ\text{C}$, write both as $R=R_0(1+\alpha T)$ and solve the pair; do not divide by $R_1$ as if it were $R_0$.
- Check the sign: metals get hotter → larger $R$; semiconductors → smaller $R$.
Electrical Energy and Power
Consider a conductor $AB$ carrying a steady current $I$ from $A$ to $B$, with a potential difference $V=V_A-V_B\gt0$ across it. In a time $\Delta t$ a charge $\Delta q=I\Delta t$ enters at $A$ and the same charge leaves at $B$. Its electric potential energy has fallen by $$\Delta U=\Delta q\,(V_A-V_B)=IV\,\Delta t.$$ If the charges moved freely this energy would become kinetic energy. But inside the conductor they keep colliding with the ions, so their average kinetic energy (their drift) stays the same; the energy is handed to the lattice at every collision and the ions vibrate more strongly — the conductor heats up. This is Joule heating. In a motor some of the energy becomes mechanical work instead, and in a battery being charged some is stored as chemical energy; but the rate at which electrical energy is delivered is always $IV$.
The power delivered to any device carrying a current $I$ with a potential difference $V$ across it is $$P=VI.$$ For a resistor of resistance $R$ (where $V=IR$) all of it becomes heat at the rate $$P=I^2R=\frac{V^2}{R}.$$ The energy delivered in time $t$ at a steady rate is $W=Pt=VIt$. The SI unit of power is the watt ($1\ \text{W}=1\ \text{J/s}=1\ \text{V A}$); electricity is sold by the kilowatt hour, $1\ \text{kWh}=3.6\times10^{6}$ J.
Which form to use? $I^2R$ is convenient when the current is fixed — resistors in series, a transmission line carrying a given current. $V^2/R$ is convenient when the potential difference is fixed — appliances in parallel on the mains. At fixed $V$ a smaller resistance draws more power, which is why a $2$ kW heater element has a lower resistance than a $1$ kW one.
Power transmission. A power station must send a power $P$ along lines of total resistance $R_c$. The current is $I=P/V$, where $V$ is the transmission voltage, so the power wasted in the lines is $$P_\text{loss}=I^2R_c=\frac{P^2R_c}{V^2}.$$ Raising $V$ ten times cuts the loss a hundred times. That is why electricity is transmitted at hundreds of kilovolts and stepped down near homes with transformers (Chapter 7).
1. Treating $\alpha$ as if it were the same for every reference temperature. Strictly $\alpha$ referred to $0\ ^\circ\text{C}$ and $\alpha$ referred to $20\ ^\circ\text{C}$ differ slightly. For small ranges it hardly matters; in two-reading problems use the strategy box above.
2. Expecting every material to resist more when hot. Semiconductors and insulators do the opposite.
3. Using the rated power at a different voltage. "$1000$ W, $230$ V" fixes the resistance $V^2/P$. At any other voltage recompute $P=V^2/R$.
4. Confusing kW and kWh. The kilowatt is a rate (power); the kilowatt hour is an amount (energy).
Not required by the CBSE syllabus. Resistance and resistivity are listed by JEE Main, NEET and JEE Advanced; conductors of varying cross-section are a JEE-style application (it uses integration) that no syllabus names.
$R=\rho l/A$ needs a uniform cross-section. If the area varies along the current, slice the conductor into thin slabs of thickness $dx$ perpendicular to the current. The slabs are in series, so their resistances $\rho\,dx/A(x)$ add (uses integration): $$R=\int_0^L\frac{\rho\,dx}{A(x)}.$$ Truncated cone (radii $a$ and $b$, length $L$): the radius grows linearly and the integral gives $R=\dfrac{\rho L}{\pi ab}$ — reducing to $\rho L/\pi a^2$ when $a=b$.
Radial leakage between two coaxial cylinders (radii $a\lt b$, length $L$) filled with a poor conductor: the current flows outwards through cylindrical shells of area $2\pi rL$, so $$R=\int_a^b\frac{\rho\,dr}{2\pi rL}=\frac{\rho}{2\pi L}\ln\frac ba.$$ This gives the leakage resistance of a coaxial cable's insulation. The board examination uses only uniform conductors.
Exercises
- 1 A device carries $0.10$ A at $1.0$ V and $0.40$ A at $2.0$ V. Find $V/I$ at each point. Is it ohmic?
- 2 Describe three different ways in which a device can fail to obey Ohm's law, with an example of each.
- 3 Give two reasons why heater elements are made of nichrome rather than copper.
- 4 Why are standard resistors made of manganin?
- 5 A nichrome wire and a copper wire have the same length and diameter. Find the ratio of their resistances.
- 6 Arrange silver, glass, pure silicon and nichrome in order of increasing resistivity.
- 7 An aluminium wire is to replace a copper wire of diameter $2.0$ mm, with the same length and resistance. What diameter must it have?
- 8 A $12$ V lamp takes $3.0$ A when lit; its cold resistance is $0.40\ \Omega$. Find its resistance when lit and the current at the instant of switching on.
- 1 A copper coil has a resistance of $5.00\ \Omega$ at $20\ ^\circ\text{C}$. Find its resistance at $100\ ^\circ\text{C}$.
- 2 A platinum thermometer has $R_0=100\ \Omega$ at $0\ ^\circ\text{C}$ and $\alpha=3.9\times10^{-3}\ ^\circ\text{C}^{-1}$. Find the temperature at which $R=125\ \Omega$.
- 3 A nichrome element ($\alpha=4.0\times10^{-4}\ ^\circ\text{C}^{-1}$) has $R=50.0\ \Omega$ at $20\ ^\circ\text{C}$. Find its resistance at $820\ ^\circ\text{C}$.
- 4 A tungsten filament ($\alpha=4.5\times10^{-3}\ ^\circ\text{C}^{-1}$) has $R=20.0\ \Omega$ at $20\ ^\circ\text{C}$ and $200\ \Omega$ when glowing. Estimate its working temperature. Why is the answer only an estimate?
- 5 A wire has resistance $4.00\ \Omega$ at $20\ ^\circ\text{C}$ and $4.80\ \Omega$ at $70\ ^\circ\text{C}$. Find $\alpha$ referred to $20\ ^\circ\text{C}$.
- 6 Use the electron model to explain why the resistivity of a metal increases with temperature.
- 7 Explain why the resistivity of a semiconductor decreases with temperature.
- 8 A carbon resistor ($\alpha=-5.0\times10^{-4}\ ^\circ\text{C}^{-1}$) and a copper resistor are joined in series. Their total resistance is $10.0\ \Omega$ and is to be independent of small changes of temperature. Find each resistance.
- 1 Find the resistance of a lamp rated $60$ W, $230$ V, and the current it draws.
- 2 The same lamp is connected to a $115$ V supply. Find the power.
- 3 A $2.0$ kW kettle is used for $15$ minutes a day for $30$ days. Find the energy used in kWh and the cost at ₹ 7 per unit.
- 4 A $10\ \Omega$ resistor carries $2.0$ A. Find the power and the heat produced in $5.0$ minutes.
- 5 Bulbs rated $100$ W and $60$ W (both for $220$ V) are joined in series across $220$ V. Which glows brighter? Find the power of each.
- 6 The same two bulbs are joined in parallel across $220$ V. Which glows brighter now?
- 7 Two heater coils work on the same mains supply. Coil $A$ has the lower resistance. Which coil gives out more heat per second, and why?
- 8 A circuit has a $5$ A fuse on the $230$ V mains. Can a $1.5$ kW iron and a $100$ W lamp be used on it at the same time?
- 1 $2.0$ MW is transmitted through lines of total resistance $4.0\ \Omega$. Find the power lost, and the percentage, at $20$ kV and at $200$ kV.
- 2 A heater coil is rated $1000$ W at $230$ V. One-tenth of its length is cut off and the rest is used on the same supply. Find the new power. Is this a safe repair?
- 3 Modelling. A $1.5$ kW kettle heats $1.0$ kg of water from $25\ ^\circ\text{C}$ to $100\ ^\circ\text{C}$. Find the least time it can take. Why is the real time longer?
- 4 The copper winding of a fan has a resistance of $0.500\ \Omega$ at $20\ ^\circ\text{C}$ and $0.580\ \Omega$ after an hour's running. Find its temperature.
- 5 Modelling. An electric car charges at $32$ A through a copper cable with two conductors, each $5.0$ m long and of cross-section $6.0\ \text{mm}^2$. Find the resistance of the conductors and the power wasted in the cable.
- 6 A $12$ V battery is rated at $60$ ampere hours. How much energy can it deliver, in joules?
E1. Board · 2 marks Sketch, on one set of axes, how the resistivity varies with temperature for (i) copper, (ii) nichrome, (iii) a semiconductor such as silicon. Explain the difference between (i) and (iii).
E2. Board · 3 marks Two bulbs rated $220$ V, $100$ W and $220$ V, $40$ W are connected in series across a $220$ V supply. Find the current and the power consumed by each bulb. Which glows brighter? Assume the resistances do not change.
E3. JEE Main The resistance of a wire is $3.0\ \Omega$ at $20\ ^\circ\text{C}$ and $3.6\ \Omega$ at $80\ ^\circ\text{C}$. Taking $R=R_0(1+\alpha T)$ with $T$ in $^\circ\text{C}$, the temperature coefficient $\alpha$ is about (A) $3.3\times10^{-3}\ ^\circ\text{C}^{-1}$ (B) $3.6\times10^{-3}\ ^\circ\text{C}^{-1}$ (C) $4.0\times10^{-3}\ ^\circ\text{C}^{-1}$ (D) $2.8\times10^{-3}\ ^\circ\text{C}^{-1}$.
E4. NEET A heater coil is cut into two equal halves and only one half is used on the same supply. The heat produced per second becomes (A) half (B) the same (C) double (D) four times.
E5. JEE Advanced (One or more correct.) Resistors $R_1$ and $R_2$ have temperature coefficients $\alpha_1=4.0\times10^{-3}\ ^\circ\text{C}^{-1}$ and $\alpha_2=-1.0\times10^{-3}\ ^\circ\text{C}^{-1}$ (at the working temperature). For small temperature changes: (A) in series, the combination's resistance does not change if $R_1:R_2=1:4$ (B) in parallel, it does not change if $R_1:R_2=4:1$ (C) in series with $R_1=R_2$, the combination has $\alpha=1.5\times10^{-3}\ ^\circ\text{C}^{-1}$ (D) $R_2$ is most likely a pure metal.
E6. JEE Main NEET A generating station supplies $1.1$ MW at $11$ kV through lines of total resistance $5.0\ \Omega$. The power lost in the lines is (A) $5.0$ kW (B) $50$ kW (C) $24$ MW (D) $0.50$ kW.
Research question. How large an error does the straight-line law $R=R_0(1+\alpha T)$ make when a platinum thermometer is used far above $100\ ^\circ\text{C}$?
Why it matters. Platinum resistance thermometers ("Pt100" sensors, $100\ \Omega$ at $0\ ^\circ\text{C}$) monitor temperatures in pharmaceutical factories, food sterilisers, power stations and hospital laboratories worldwide. An international standard describes their resistance with a small quadratic correction to the linear law. Knowing when the correction matters is a real calibration question.
What to do.
- For $T\ge0\ ^\circ\text{C}$ the standard sensor follows $R=R_0\left(1+AT+BT^2\right)$ with $R_0=100\ \Omega$, $A=3.9083\times10^{-3}\ ^\circ\text{C}^{-1}$ and $B=-5.775\times10^{-7}\ ^\circ\text{C}^{-2}$. Compute $R$ at $0,\ 100,\ 200,\ 300$ and $400\ ^\circ\text{C}$.
- Find the "average" coefficient between $0$ and $100\ ^\circ\text{C}$: $\alpha=\dfrac{R_{100}-R_0}{100R_0}$.
- Pretend you only know this $\alpha$. Use the linear law to convert each true resistance back into a temperature. Tabulate the error (linear reading minus true temperature).
- Plot the error against temperature. Over what range is the linear law good to within $1\ ^\circ\text{C}$?
Tools: Spreadsheet or calculator; graph paper or plotting software.
Hand in: Your table, the error graph, and a recommendation on when the quadratic term must be used.
Going further. The quadratic term makes $dR/dT$ fall as $T$ rises. What does that mean for the thermometer's sensitivity (ohms per degree) at $400\ ^\circ\text{C}$ compared with $0\ ^\circ\text{C}$?
🧪 Self-check quiz
Q1. As the temperature of pure silicon rises, its resistivity
Q2. Manganin is used for standard resistors mainly because it has
Q3. A heater coil is replaced by one of half the resistance, on the same mains supply. The power
Q4. One kilowatt hour is
Q5. The $I$–$V$ graph of an ohmic conductor at constant temperature is