Reference

Glossary

Every technical word in the course and what it means in plain language, with flashcards for practice.

Every technical term in the course, with a plain-language meaning. On every page these words are marked with a dotted underline: hover or tap one to see its meaning. The “Used in” links point to the sections where each term appears.

Flashcards — term ⇄ meaning
Ch 1 · Chemical Reactions and Equations
TermMeaningUsed in
antioxidantA substance added to food containing fats and oils to slow down their oxidation (rancidity), e.g. vitamin E.1.3
balanced chemical equationAn equation with the same number of atoms of each element on both sides, using the smallest whole-number coefficients, e.g. $\mathrm{2Mg + O_{2} \rightarrow 2MgO}$.1.1 1.2 1.3 2.1
chemical reactionA process in which substances (reactants) change into new substances (products) with different properties, because their atoms are regrouped.1.1 1.3 4.3
combination reactionA reaction in which two or more reactants form a single product, $\mathrm{A + B \rightarrow AB}$, e.g. $\mathrm{CaO + H_{2}O \rightarrow Ca(OH)_{2}}$.1.2
corrosionThe slow eating away of a metal by substances around it such as moisture, oxygen, acids or sulphur compounds: iron rusts, silver turns black, copper turns green.1.3 2.1 3.1 3.3
decomposition reactionA reaction in which a single reactant breaks down into two or more simpler products, $\mathrm{AB \rightarrow A + B}$, using energy supplied as heat, light or electricity.1.2
displacement reactionA reaction in which a more reactive element pushes a less reactive one out of its compound, $\mathrm{A + BC \rightarrow AC + B}$, e.g. $\mathrm{Fe + CuSO_{4} \rightarrow FeSO_{4} + Cu}$.1.2 2.1 3.1
double displacement reactionA reaction in which two compounds exchange ions to form two new compounds, $\mathrm{AB + CD \rightarrow AD + CB}$, e.g. $\mathrm{Na_{2}SO_{4} + BaCl_{2} \rightarrow BaSO_{4} + 2NaCl}$.1.2 2.1
electrolytic decompositionDecomposition brought about by passing an electric current, e.g. water splitting into hydrogen and oxygen in the volume ratio 2 : 1.1.2 2.3 3.3
endothermic reactionA reaction that takes in energy from the surroundings, e.g. most decompositions and photosynthesis.1.2
exothermic reactionA reaction that gives out energy (usually heat) to the surroundings, e.g. burning, respiration, quicklime with water.1.2 2.1
law of conservation of massMass is neither created nor destroyed in a chemical reaction: in a closed system the total mass of the products equals the total mass of the reactants.1.1 1.3 4.3
oxidationGain of oxygen or loss of hydrogen by a substance, e.g. $\mathrm{2Cu + O_{2} \rightarrow 2CuO}$. (In Class 11: loss of electrons.)1.2 1.3 4.3 4.4
oxidising agentThe substance that brings about oxidation by giving oxygen (or taking hydrogen); it is itself reduced.1.3 2.3 3.1 4.3
photolytic decompositionDecomposition brought about by light, e.g. white silver chloride turning grey in sunlight as silver forms.1.2
precipitateAn insoluble solid that separates out of a solution during a reaction, e.g. yellow lead iodide $\mathrm{PbI_{2}}$; given the state symbol (s).1.1 1.2 2.1 4.4
precipitation reactionAny reaction that produces a precipitate (an insoluble solid) from solutions; most are double displacement reactions.1.2
productA new substance formed in a chemical reaction; products are written on the right of the arrow.1.1 1.2 1.3 2.1
rancidityThe bad smell and taste of food containing fats and oils after they are oxidised by air; slowed by antioxidants, airtight packing, nitrogen flushing and cold storage.1.3
reactantA substance present at the start of a chemical reaction; reactants are written on the left of the arrow.1.1 1.2 1.3 3.3
redox reactionA reaction in which one substance is oxidised and another is reduced at the same time, e.g. $\mathrm{CuO + H_{2} \rightarrow Cu + H_{2}O}$.1.3 3.3
reducing agentThe substance that brings about reduction by taking oxygen (or giving hydrogen); it is itself oxidised, e.g. carbon, hydrogen, carbon monoxide.1.3 3.3
reductionLoss of oxygen or gain of hydrogen by a substance, e.g. $\mathrm{CuO}$ becoming $\mathrm{Cu}$ when heated in hydrogen. (In Class 11: gain of electrons.)1.3 3.3 4.3
rustReddish-brown, flaky hydrated iron(III) oxide, $\mathrm{Fe_{2}O_{3}\cdot xH_{2}O}$, formed when iron is exposed to both oxygen and water.1.1 1.3 3.1 3.3
skeletal equationA chemical equation with the correct formulas but not yet balanced, e.g. $\mathrm{Mg + O_{2} \rightarrow MgO}$.1.1 1.2
state symbolA label after a formula showing its physical state: (s) solid, (l) liquid, (g) gas, (aq) dissolved in water.1.1 1.2 2.1 2.3
thermal decompositionDecomposition brought about by heating, e.g. $\mathrm{CaCO_{3} \rightarrow CaO + CO_{2}}$ in a lime kiln.1.2
Ch 2 · Acids, Bases and Salts
TermMeaningUsed in
acidA substance that tastes sour, turns blue litmus red and, in water, gives hydrogen ions $\mathrm{H^{+}(aq)}$ (hydronium ions), e.g. $\mathrm{HCl}$, $\mathrm{H_{2}SO_{4}}$, citric acid.1.1 1.2 1.3 2.1
acid rainRain with a pH below 5.6, caused by oxides of sulphur and nitrogen dissolving in rain water to form sulphuric and nitric acids.2.1 2.2
acidic oxideAn oxide, usually of a non-metal, that reacts with a base to give a salt and water, e.g. $\mathrm{CO_{2}}$ with lime water.2.1 2.2 3.1
alkaliA base that dissolves in water, giving hydroxide ions $\mathrm{OH^{-}(aq)}$, e.g. $\mathrm{NaOH}$, $\mathrm{KOH}$, $\mathrm{Ca(OH)_{2}}$, $\mathrm{NH_{4}OH}$. All alkalis are bases, but not all bases are alkalis.2.1 2.3 3.1 3.2
anhydrousWithout water of crystallisation, e.g. white $\mathrm{CuSO_{4}}$, the form left when blue copper sulphate crystals are heated.1.3 2.3
antacidA mild base, such as milk of magnesia or baking soda, taken to neutralise excess acid in the stomach.2.1 2.2 2.3 3.2
baking powderA mixture of baking soda and a mild solid acid such as tartaric acid; it releases carbon dioxide in water and makes cakes and bread rise.2.3
baking sodaSodium hydrogencarbonate $\mathrm{NaHCO_{3}}$, a mild base used in cooking, antacids and fire extinguishers; on heating it gives $\mathrm{Na_{2}CO_{3}}$, water and carbon dioxide.1.1 1.2 2.1 2.2
baseA substance that tastes bitter, feels soapy, turns red litmus blue and neutralises an acid to give a salt and water, e.g. $\mathrm{NaOH}$, $\mathrm{CuO}$, $\mathrm{Mg(OH)_{2}}$.1.2 2.1 2.2 2.3
basic oxideAn oxide, usually of a metal, that reacts with an acid to give a salt and water, e.g. $\mathrm{CuO + 2HCl \rightarrow CuCl_{2} + H_{2}O}$.2.1 3.1
bleaching powderCalcium oxychloride $\mathrm{CaOCl_{2}}$, made by passing chlorine over dry slaked lime; used for bleaching and for disinfecting drinking water.2.3
chlor-alkali processThe electrolysis of brine, giving sodium hydroxide, chlorine (at the anode) and hydrogen (at the cathode): $\mathrm{2NaCl + 2H_{2}O \rightarrow 2NaOH + Cl_{2} + H_{2}}$.2.3
dilutionLowering the concentration of a solution by adding water. Diluting an acid raises its pH towards 7 (never beyond); diluting a base lowers its pH towards 7.2.1 2.2
end pointThe stage in a neutralisation at which exactly enough base (or acid) has been added to use up the other, shown by the indicator changing colour.2.2
gypsumHydrated calcium sulphate $\mathrm{CaSO_{4}\cdot 2H_{2}O}$; heating it at 373 K gives plaster of Paris.2.3
hydronium ionThe ion $\mathrm{H_{3}O^{+}}$, formed when a hydrogen ion from an acid joins a water molecule: $\mathrm{H^{+} + H_{2}O \rightarrow H_{3}O^{+}}$.2.1 2.2
indicatorA substance that shows by a change of colour (or smell) whether a solution is acidic or basic, e.g. litmus, phenolphthalein, methyl orange, turmeric.2.1 2.2 2.3
litmusA natural purple dye from lichens: red in acids, blue in bases. Blue litmus paper turns red in an acid; red litmus paper turns blue in a base.2.1 2.2 2.3 3.1
neutralisationThe reaction of an acid with a base to give a salt and water, e.g. $\mathrm{NaOH + HCl \rightarrow NaCl + H_{2}O}$; in ions, $\mathrm{H^{+} + OH^{-} \rightarrow H_{2}O}$.1.2 2.1 2.2 2.3
olfactory indicatorAn indicator whose smell changes: the smell of onion, vanilla essence or clove oil cannot be detected in a basic solution but stays in an acidic one.2.1
pH scaleA scale from 0 to 14 that shows how acidic or basic a solution is: below 7 acidic, 7 neutral, above 7 basic. The lower the pH, the more hydronium ions $\mathrm{H_{3}O^{+}}$ the solution has.2.1 2.2 2.3 4.4
phenolphthaleinA synthetic indicator that is colourless in acidic and neutral solutions and pink in basic solutions.2.1 2.2 2.3
plaster of ParisA white powder $\mathrm{CaSO_{4}\cdot\tfrac{1}{2}H_{2}O}$ that sets into hard gypsum when mixed with water; used for casts, toys and smoothing walls.2.3
saltAn ionic compound formed when the hydrogen ions of an acid are replaced by a metal (or ammonium) ion, e.g. $\mathrm{NaCl}$, $\mathrm{K_{2}SO_{4}}$, $\mathrm{CuSO_{4}}$; the other product of neutralisation besides water.1.1 1.2 1.3 2.1
strong acidAn acid that gives almost all its hydrogen ions to water, e.g. $\mathrm{HCl}$, $\mathrm{H_{2}SO_{4}}$, $\mathrm{HNO_{3}}$. It has a low pH and reacts fast with metals and carbonates.2.2 2.3 4.4
strong baseA base that gives almost all its hydroxide ions in water, e.g. $\mathrm{NaOH}$ and $\mathrm{KOH}$.2.1 2.2 2.3
universal indicatorA mixture of dyes that shows a different colour at each pH (red for strong acids, green at pH 7, violet for strong bases), so the pH can be read approximately.2.2 2.3
washing sodaHydrated sodium carbonate $\mathrm{Na_{2}CO_{3}\cdot 10H_{2}O}$, a basic salt used in glass, soap and paper industries and to remove hardness of water.2.1 2.2 2.3 3.2
water of crystallisationThe fixed number of water molecules that form part of the crystal of a hydrated salt, e.g. 5 in $\mathrm{CuSO_{4}\cdot 5H_{2}O}$.1.2 2.3
weak acidAn acid that gives only a few hydrogen ions to water, e.g. ethanoic acid $\mathrm{CH_{3}COOH}$ and carbonic acid $\mathrm{H_{2}CO_{3}}$.2.2 2.3 4.4
weak baseA base that gives only a few hydroxide ions in water, e.g. $\mathrm{NH_{4}OH}$ and $\mathrm{Mg(OH)_{2}}$.2.1 2.2 2.3
Ch 3 · Metals and Non-metals
TermMeaningUsed in
alloyA homogeneous mixture of two or more metals, or of a metal and a non-metal, e.g. steel, brass, bronze, solder, stainless steel; usually harder and more corrosion-resistant than the main metal.1.3 3.3
amphoteric oxideA metal oxide that reacts with both acids and bases to give salt and water, e.g. $\mathrm{Al_{2}O_{3}}$ and $\mathrm{ZnO}$.3.1
anionA negatively charged ion, formed when an atom (usually a non-metal) gains electrons, e.g. $\mathrm{Cl^{-}}$, $\mathrm{O^{2-}}$.3.2
anodeThe positive electrode in electrolysis, where negative ions lose electrons (oxidation); in refining, the impure metal dissolves from it.2.3 3.1 3.2 3.3
aqua regiaA freshly prepared 3 : 1 mixture of concentrated hydrochloric acid and concentrated nitric acid, able to dissolve gold and platinum.3.1
calcinationHeating a carbonate ore strongly in a limited supply of air to convert it into the oxide, e.g. $\mathrm{ZnCO_{3} \rightarrow ZnO + CO_{2}}$.3.3
cathodeThe negative electrode in electrolysis, where positive ions gain electrons (reduction) and the metal is deposited.2.3 3.2 3.3
cationA positively charged ion, formed when an atom (usually a metal) loses electrons, e.g. $\mathrm{Na^{+}}$, $\mathrm{Mg^{2+}}$.3.2
ductileAble to be drawn out into thin wires, as copper and gold can.3.1
electrolytic refiningPurifying a metal by making the impure metal the anode and a strip of pure metal the cathode in a solution of its salt; the pure metal deposits on the cathode and impurities fall as anode mud.3.3
formula unitThe simplest ratio of ions in an ionic compound, e.g. $\mathrm{NaCl}$ ($1:1$) or $\mathrm{MgCl_{2}}$ ($1:2$); an ionic crystal has no separate molecules.2.3 3.2
galvanisationCoating iron or steel with a layer of zinc to prevent rusting; zinc, being more reactive, is attacked first even if the coating is scratched.1.3 3.1 3.3
gangueThe earthy impurities (sand, soil, rock) mixed with an ore, removed during enrichment.3.3
ionAn atom or group of atoms with an electric charge because it has lost or gained electrons, e.g. $\mathrm{Na^{+}}$, $\mathrm{Cl^{-}}$, $\mathrm{O^{2-}}$.1.1 1.2 1.3 2.1
ionic bondThe strong electrostatic attraction between oppositely charged ions formed by the transfer of electrons from a metal atom to a non-metal atom.3.2 4.1
ionic compoundA compound made of positive and negative ions held together by ionic bonds, e.g. $\mathrm{NaCl}$, $\mathrm{MgO}$; it is a hard, brittle solid with a high melting point that conducts only when molten or dissolved.2.3 3.2 4.1
lustreThe shine of a freshly cut or polished metal surface; most metals are lustrous, most non-metals are dull (iodine is a shiny exception).3.1
malleableAble to be hammered or rolled into thin sheets without breaking, as gold, silver and aluminium can.3.1 3.2
noble metalA metal at the bottom of the reactivity series, such as gold, silver or platinum, that hardly reacts with oxygen, water or acids.3.1
octetA full outermost shell: eight electrons (octet), or two for the first shell (duplet). Atoms react to reach this stable noble-gas arrangement.3.2 4.1
oreA mineral from which a metal can be extracted profitably, e.g. haematite $\mathrm{Fe_{2}O_{3}}$, bauxite, cinnabar $\mathrm{HgS}$.3.1 3.3
reactivity seriesThe list of metals in decreasing order of reactivity: K, Na, Ca, Mg, Al, Zn, Fe, Pb, [H], Cu, Hg, Ag, Au. A metal displaces any metal lower in the list from its salt solution.1.2 2.1 3.1 3.3
roastingHeating a sulphide ore strongly in excess air to convert it into the oxide, e.g. $\mathrm{2ZnS + 3O_{2} \rightarrow 2ZnO + 2SO_{2}}$.3.3
sonorousProducing a ringing sound when struck; metals are sonorous, which is why bells are made of metal.3.1
thermite reactionThe reaction of a metal oxide with aluminium that gives molten metal and a great deal of heat, e.g. $\mathrm{Fe_{2}O_{3} + 2Al \rightarrow Al_{2}O_{3} + 2Fe}$; used to weld railway tracks.1.2 3.3
valence electronAn electron in the outermost shell of an atom; valence electrons decide how the atom reacts.3.2
Ch 4 · Carbon and its Compounds
TermMeaningUsed in
addition reactionA reaction in which atoms add across the double or triple bond of an unsaturated compound, e.g. $\mathrm{C_{2}H_{4} + H_{2} \rightarrow C_{2}H_{6}}$.4.3
alcoholA compound containing the hydroxyl group $-\mathrm{OH}$ on a carbon chain, e.g. ethanol; names end in -ol.2.1 4.2 4.3 4.4
aldehydeA compound containing the group $-\mathrm{CHO}$ at the end of a carbon chain, e.g. ethanal; names end in -al.4.2
alkaline potassium permanganateAlkaline potassium permanganate and acidified potassium dichromate are oxidising agents that turn ethanol into ethanoic acid; the permanganate loses its purple colour and the dichromate turns from orange to green.4.3
allotropeOne of the different forms of the same element in the same physical state, with the atoms arranged differently, e.g. diamond and graphite are allotropes of carbon.4.1
carbon monoxideA poisonous gas CO formed when carbon compounds burn in too little oxygen.1.1 1.3 3.1 4.3
carboxylic acidA compound containing the group $-\mathrm{COOH}$, e.g. ethanoic acid; names end in -oic acid.4.2 4.3 4.4
catalystA substance that speeds up a chemical reaction without being used up, e.g. nickel in hydrogenation.1.1 4.3 4.4
catenationThe ability of atoms of an element to join one another into long chains, branched chains and rings; carbon shows it strongly because the C–C bond is strong.4.2
combustionThe burning of a substance in oxygen with release of heat and light; a carbon compound burning completely gives carbon dioxide and water.1.1 1.3 4.1 4.3
covalent bondA bond formed by the sharing of a pair of electrons between two atoms, each shared pair counting towards the outer shell of both atoms, e.g. in $\mathrm{H_{2}}$, $\mathrm{CH_{4}}$ and $\mathrm{CO_{2}}$.4.1
covalent compoundA compound made of molecules whose atoms are joined by covalent bonds; usually has low melting and boiling points and does not conduct electricity.4.1
dehydrationThe removal of water from a compound; ethanol heated with excess concentrated sulphuric acid at 443 K is dehydrated to ethene.4.4
denatured alcoholEthanol made unfit for drinking by adding poisonous methanol and a bad-tasting coloured substance, so that industrial alcohol is not misused.4.4
detergentA cleaning agent made of sodium salts of sulphonic acids (or ammonium salts) with long hydrocarbon chains; it forms micelles but its calcium and magnesium salts are soluble, so it works in hard water.2.3 4.4
double bondTwo shared pairs of electrons between two atoms, drawn as two lines, as in O=O or C=C.4.1 4.2 4.3
electron-dot structureA diagram of a molecule showing the outer electrons of its atoms as dots and crosses, with shared pairs between the atoms and lone pairs on them.4.1
esterA sweet-smelling compound formed from a carboxylic acid and an alcohol, e.g. ethyl ethanoate $\mathrm{CH_{3}COOC_{2}H_{5}}$; used in perfumes and flavourings.4.4
esterificationThe reaction of a carboxylic acid with an alcohol, in the presence of a few drops of concentrated sulphuric acid, to give an ester and water.4.4
fullereneAn allotrope of carbon made of hollow cage-like molecules; the first, $\mathrm{C_{60}}$, has 60 carbon atoms in a football shape.4.1
functional groupAn atom or group of atoms, such as $-\mathrm{OH}$, $-\mathrm{CHO}$ or $-\mathrm{COOH}$, that determines the chemical properties of a carbon compound.4.2 4.3
glacial ethanoic acidPure ethanoic acid; it freezes to ice-like crystals below 290 K (17 °C).2.2 4.4
hard waterWater containing dissolved calcium and magnesium salts, with which soap forms an insoluble scum.2.3 4.4
homologous seriesA family of carbon compounds with the same functional group and general formula, whose successive members differ by $-\mathrm{CH_{2}}-$ ($14\ \mathrm{u}$).4.2
hydrocarbonA compound containing only carbon and hydrogen, such as methane $\mathrm{CH_{4}}$ or ethene $\mathrm{C_{2}H_{4}}$.4.2 4.3 4.4
hydrogenationThe addition of hydrogen to an unsaturated compound in the presence of a nickel or palladium catalyst; used to turn vegetable oils into solid vanaspati ghee.2.3 4.3
hydrophilic and hydrophobicHydrophilic (water-loving) describes the ionic head of a soap molecule, which dissolves in water; hydrophobic (water-hating) describes its hydrocarbon tail, which dissolves in oil.4.4
incomplete combustionBurning in a limited supply of oxygen, which gives carbon monoxide and soot as well as carbon dioxide and water; the flame is yellow and sooty.4.3
IUPAC nameThe systematic name of a compound given by the rules of the International Union of Pure and Applied Chemistry: root for the number of carbons plus suffix or prefix for the functional group.1.1 4.2
ketoneA compound containing the group $>\mathrm{C{=}O}$ inside a carbon chain, e.g. propanone; names end in -one.4.2
lone pairA pair of outer electrons that belongs to one atom and is not shared in a bond, e.g. the two lone pairs on oxygen in water.4.1
micelleA spherical cluster of soap or detergent molecules in water, with the oil-loving tails inwards around a droplet of oil and the water-loving heads outwards.4.4
moleculeThe smallest independent unit of a covalent substance, a group of atoms joined by covalent bonds, e.g. $\mathrm{H_{2}O}$, $\mathrm{CH_{4}}$.1.1 1.2 2.1 2.2
saponificationThe reaction of an ester with sodium hydroxide to give an alcohol and the sodium salt of the acid; applied to fats and oils it gives soap and glycerol.4.4
saturated compoundA hydrocarbon in which the carbon atoms are joined only by single bonds; the alkanes, general formula $\mathrm{C_{n}H_{2n+2}}$.4.2 4.3
scumThe insoluble calcium or magnesium salt of the soap acid formed when soap is used in hard water, e.g. calcium stearate.4.4
single bondOne shared pair of electrons between two atoms, drawn as one line, as in H–H or C–H.4.1 4.2 4.3
soapThe sodium or potassium salt of a long-chain carboxylic acid, e.g. sodium stearate $\mathrm{C_{17}H_{35}COONa}$, with an ionic head and a hydrocarbon tail.2.1 2.2 2.3 4.4
sootFine black particles of unburnt carbon formed in incomplete combustion; it blackens vessels held in a yellow flame.1.1 4.3 4.4
structural formulaA drawing of a molecule showing its atoms with a line for each shared pair, e.g. H–O–H for water.4.1 4.2
structural isomersCompounds with the same molecular formula but different arrangements of atoms, e.g. butane and 2-methylpropane, both $\mathrm{C_{4}H_{10}}$.4.2
substitution reactionA reaction in which an atom or group of a compound is replaced by another, e.g. methane and chlorine in sunlight give chloromethane and hydrogen chloride.4.3
triple bondThree shared pairs of electrons between two atoms, drawn as three lines, as in N≡N or C≡C.4.1 4.2 4.3
unsaturated compoundA hydrocarbon with at least one double bond (alkenes, $\mathrm{C_{n}H_{2n}}$) or triple bond (alkynes, $\mathrm{C_{n}H_{2n-2}}$) between carbon atoms.4.2 4.3
vanaspati gheeSolid saturated fat made by hydrogenating liquid vegetable oils with a nickel catalyst.4.3
vinegarA 5–8 % solution of ethanoic acid in water, used for pickles and as a preservative.1.1 1.3 2.1 2.2